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Ozone’s Long Path to Recovery

December 19, 2013

The holes that formed in the
ozone layer over Antarctica in 2011 and 2012 are a study in contrasts. The 2011
hole (top left) ranked among the ten largest recorded since the 1980s, while the
2012 hole (top right) was the second smallest. Why were they so different? Is it
a sign that stratospheric ozone is recovering? These are the questions NASA
scientists Anne Douglass, Natalya Kramarova, and Susan Strahan asked as they
examined the holes using data from instruments on NASA’s Aura and NASA/NOAA’s
Suomi NPP satellites.

The images above represent the
typical method of gauging the ozone hole. They show the extent (the geographic
area covered) and the depth (the concentration of ozone from top to bottom in
the atmosphere) as measured by Aura’s Ozone Monitoring Instrument. Blues and
purples represent the lowest ozone levels. Each image shows the day of maximum
extent—when the ozone hole was largest that year.

But the view of area doesn’t tell
the whole story, said Douglass. It says nothing about the chemistry or
atmospheric dynamics that give the hole its shape. And if we don’t know why the
size and depth of the hole varies, it is impossible to know if policies meant to
reduce ozone depletion (such as the Montreal Protocol) are having an impact.
2011 and 2012 offer prime examples.

The Antarctic ozone hole forms in
the southern spring when chlorine and other ozone depleting chemicals interact
with sunlight to destroy ozone. It would be easy to assume that a larger ozone
hole means more chemicals were present, but the real picture is more

“2011 would have had less ozone
even without ozone depleting chemicals,” said Strahan. Stratospheric ozone is
naturally produced in the tropics and transported to the poles. In 2011, winds
blew less ozone to Antarctica so there was less to destroy. Strahan also found
less chlorine in the atmosphere over Antarctica in 2011 than in other years, but
because there was less ozone, a large hole developed.

In 2012, ozone depletion in the
lower atmosphere was severe, said Kramarova. But in early October of 2012, winds
blew in more ozone at higher levels, above the depleted area. The high-level
ozone masked the destruction at lower altitudes, and so the hole looks small in
the OMI image.

All of this means that the size
of the ozone hole is not the only indicator of how well policies to control
ozone-depleting chemicals are working. “Ozone holes with smaller areas and a
larger total amount of ozone are not necessarily evidence of recovery
attributable to the expected chlorine decline,” said Strahan. “That assumption
is like trying to understand what’s wrong with your car’s engine without lifting
the hood.”

In fact, the fluctuating size of
the ozone hole has not been tied to chlorine concentrations since the 1990s, as
shown in the two graphs above. The first graph depicts chlorine concentrations,
and the second shows ozone hole size over time. In the 1980s, ozone hole area
increased in step with chlorine concentrations, but that relationship broke down
in the 1990s. The atmosphere became saturated with chlorine, and the additional
chlorine did not have enough ozone to react with. Adding more chlorine in these
conditions no long increases ozone depletion, and so the size of the ozone hole
was no longer directly related to chlorine concentrations.

Since the 1990s, the ozone hole
area has been controlled entirely by weather. The chemicals that destroy ozone
are so long-lived that Douglass, Strahan, and Kramarova don’t expect to see the
impact of the Montreal Protocol until about 2025 when chlorine levels drop below
saturation. Full recovery should occur sometime between 2058 and 2090, based on
projections of levels of ozone-depleting gases and their break-down and


NASA images courtesy of Ozone
Watch. Graphs from Paul Newman and Eric Nash, NASA Goddard Space Flight Center.
Caption by Holli Riebeek.
Instrument: Aura – OMI